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Key Documents

481483

Sigma-Aldrich

Sodium tetraethylborate

97%

Synonym(s):

Et4BNa

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About This Item

Linear Formula:
(C2H5)4BNa
CAS Number:
Molecular Weight:
150.05
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

reaction suitability

core: boron
reagent type: catalyst

mp

140-142 °C (lit.)

SMILES string

[Na+].CC[B-](CC)(CC)CC

InChI

1S/C8H20B.Na/c1-5-9(6-2,7-3)8-4;/h5-8H2,1-4H3;/q-1;+1

InChI key

SZSBMTRYJRHYNI-UHFFFAOYSA-N

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General description

Sodium tetraethylborate (NaBEt4) is an air and moisture-sensitive pyrophoric organoboron compound. It is very reactive in the presence of certain organometallic species and is used as an ethyl transfer reagent.

Application

Sodium tetraethylborate can be used as a derivatizing agent in the GC-MS analyses of fenbutatin oxide and alkyl tin compounds.

related product

Pictograms

Flame

Signal Word

Danger

Hazard Statements

Hazard Classifications

Pyr. Sol. 1 - Water-react 2

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Andrés Rodríguez-Cea et al.
Environmental science and pollution research international, 23(5), 4876-4885 (2015-11-08)
The degradation of butyltin compounds in surface water samples under different storage conditions has been studied. A triple spike solution, containing monobutyltin (MBT), dibutyltin (DBT) and tributyltin (TBT) labelled with a different tin isotope, was added to the sample to
Stig Valdersnes et al.
Journal of AOAC International, 102(1), 278-285 (2018-12-31)
Organotin compounds are anthropogenic metal species with multiple uses as pesticides, preservatives, antifouling agents, biocides, and catalysts. Butyltins are the main organotin compounds found in biota, and the highest levels are found in marine foodstuffs. In this paper, we present
M Leermakers et al.
Analytical and bioanalytical chemistry, 381(6), 1272-1280 (2005-02-16)
Monobutyltin (MBuT), dibutyltin (DBuT), and tributyltin (TBuT) mixtures have been separated and quantified by gas chromatography with pulsed flame-photometric detection (GC-PFPD). The compounds were first derivatized with NaBEt4, then extracted with hexane and injected into the GC in splitless mode.
Feras Abujaber et al.
Mikrochimica acta, 186(7), 400-400 (2019-06-12)
Magnetite (Fe3O4) nanoparticles were modified with nanocellulose and are showed to be a useful sorbent for magnetic solid-phase extraction of mercury species. Speciation analysis was performed by using gas chromatography coupled to atomic fluorescence detection (GC-pyro-AFS). The magnetic properties of
Andrea Santa-Rios et al.
Chemosphere, 266, 129001-129001 (2020-11-30)
The artisanal and small-scale gold mining (ASGM) sector uses the most mercury (Hg) worldwide. Despite health concerns associated with high Hg exposures in these communities, ASGM sites are often situated in resource limited and remote regions which challenge traditional human

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