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480886

Sigma-Aldrich

Sodium borohydride

greener alternative

granular, 99.99% trace metals basis

Synonym(s):

Sodium tetrahydridoborate

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About This Item

Linear Formula:
NaBH4
CAS Number:
Molecular Weight:
37.83
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

99.99% trace metals basis

form

granular

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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mp

>300 °C (dec.) (lit.)

greener alternative category

SMILES string

[BH4-].[Na+]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI key

YOQDYZUWIQVZSF-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Nanocrystalline superlattices in gold colloid solution have been prepared by ligand-induction using AuCl3 reduced with sodium borohydride. Nucleophilic addition of hydride ion from sodium borohydride is an inexpensive alternative method for the Baylis-Hillman reaction to form [E]-a-methylcinnamic acids. A reductant solution composed of NaBH4 and NaOH was used to form mercury cold vapor. NaBH4 may be used to generate hydrogen by catalytic hydrolysis.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Metal Borohydrides as Hydrogen Storage Materials
Soloveichik GL
Material Matters, 2(2), 11-11 (2007)

Articles

An article about metal borohydrides as hydrogen storage materials

Single molecule electronics is the endeavour of constructing electronic circuitry with single molecules as the fundamental building block.

Noble-metal nanostructures are widely used in a variety of applications ranging from catalysis to electronics, surface plasmon resonance (SPR), surface-enhanced Raman scattering (SERS), and biomedical research.

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