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455067

Sigma-Aldrich

4-(Hydroxymethyl)-1,3-dioxolan-2-one

Synonym(s):

(2-Oxo-1,3-dioxolan-4-yl)methanol, 3-Hydroxypropene carbonate, 3-Hydroxypropylene carbonate, 4-Methylolethylene carbonate, Glycerin carbonate, Glycerol 1,2-carbonate

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About This Item

Empirical Formula (Hill Notation):
C4H6O4
CAS Number:
931-40-8
Molecular Weight:
118.09
EC Number:
213-235-0
MDL number:
MFCD00085561
UNSPSC Code:
12352100
PubChem Substance ID:
24869019
NACRES:
NA.22

refractive index

n20/D 1.469 (lit.)

Quality Level

100

bp

137-140 °C/0.5 mmHg (lit.)

density

1.4 g/mL at 25 °C (lit.)

SMILES string

OCC1COC(=O)O1

InChI

1S/C4H6O4/c5-1-3-2-7-4(6)8-3/h3,5H,1-2H2

InChI key

JFMGYULNQJPJCY-UHFFFAOYSA-N

Related Categories

Application

4-(Hydroxymethyl)-1,3-dioxolan-2-one can be used as a building block to synthesize:
  • 4-[(prop-2-en-1-yloxy)methyl]-1,3-dioxolan-2-one (AGC) via Williamson ether synthesis with 3-bromoprop-1-ene.
  • Hyperbranched polyethers via copolymerization with cyclic carbonate containing phthalimide moieties.
  • (2-Oxo-1,3-dioxolan-4-yl)methyl benzeneacetate by reacting with phenylacetyl chloride.

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCB2708V
MKBF8227V
02018JI
12303MI

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Cyclic carbonates obtained by reactions of alkali metal carbonates with epihalohydrins.
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An ion-moderated partition high-performance liquid chromatography method was developed for the separation and identification of common organic carbonates. The separation of organic carbonates was achieved on an ion exclusion column with an exchangeable hydrogen ion. An isocratic, aqueous mobile phase
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