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Key Documents

449075

Sigma-Aldrich

Methyl 2-naphthoate

97%

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About This Item

Linear Formula:
C10H7CO2CH3
CAS Number:
Molecular Weight:
186.21
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

solid

bp

290 °C (lit.)

mp

75-77 °C (lit.)

SMILES string

COC(=O)c1ccc2ccccc2c1

InChI

1S/C12H10O2/c1-14-12(13)11-7-6-9-4-2-3-5-10(9)8-11/h2-8H,1H3

InChI key

IODOXLXFXNATGI-UHFFFAOYSA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Cucurbit [8] uril-mediated photodimerization of alkyl 2-naphthoate in aqueous solution.
Lei L, et al.
Tetrahedron Letters, 49(9), 1502-1505 (2008)
Molecular association of singlet excited state methyl 2-naphthoate; effects of excimer formation on photocycloaddition.
Chow YL and Johansson CI.
Research on Chemical Intermediates, 19(3), 191-209 (1993)
Stereochemistry of a cubane-like photodimer of methyl 2-naphthoate.
Lei L, et al.
Tetrahedron Letters, 47(27), 4725-4727 (2006)
Photochemical synthesis. VI. The formation of benzosemibullvalene derivatives in the photoaddition of diphenylacetylene to methyl 2-naphthoate, a degenerate thermal isomerization of the benzosemibullvalene skeleton.
Sugowdz G, et al.
Australian Journal of Chemistry, 26(1), 147-171 null
Rafał Frański et al.
Journal of mass spectrometry : JMS, 53(5), 379-384 (2018-02-15)
Gas phase decompositions of protonated methyl benzoate and its conjugates have been studied by using electrospray ionization-collision induced dissociation-tandem mass spectrometry. Loss of CO2 molecule, thus transfer of methyl group, has been observed. In order to better understand this process

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