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Key Documents

388297

Sigma-Aldrich

Ferrocenium hexafluorophosphate

97%

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About This Item

Empirical Formula (Hill Notation):
C10H10F6FeP
CAS Number:
Molecular Weight:
331.00
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

powder

reaction suitability

core: iron
reagent type: catalyst

SMILES string

[Fe+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F

InChI

1S/2C5H5.F6P.Fe/c2*1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-5H;;/q;;-1;+1

InChI key

JTRCXNUQIANBAN-UHFFFAOYSA-N

Application

The ferrocenium cation has been used to prepare catalysts for the asymmetric epoxidation of olefins, carbonylations of nitroaromatics, and the isomerization of a strained diene.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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