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264237

Sigma-Aldrich

1,2-Dibromo-4,5-difluorobenzene

98%

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About This Item

Linear Formula:
Br2C6H2F2
CAS Number:
Molecular Weight:
271.88
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

liquid

mp

33-35 °C (lit.)

functional group

bromo
fluoro

SMILES string

Fc1cc(Br)c(Br)cc1F

InChI

1S/C6H2Br2F2/c7-3-1-5(9)6(10)2-4(3)8/h1-2H

InChI key

JTEZQWOKRHOKDG-UHFFFAOYSA-N

Application

1,2-Dibromo-4,5-difluorobenzene has been used in the preparation of:
  • 2,2′-dibromo-4,4′,5,5′-tetrafluorobiphenyl
  • 2-(2,3-dibromo-5,6-difluorophenyl)propan-2-ol

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

111.2 °F - closed cup

Flash Point(C)

44 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of biphenylenes and tetraphenylenes using copper-catalyzed coupling of arylzinc intermediates.
Kabir SMH, et al.
Journal of the Chemical Society. Perkin Transactions 1, 2, 159-165 (2001)
The lithiation of fluorinated benzenes and its dependence on solvent and temperature.
Coe PL, et al.
Journal of the Chemical Society. Perkin Transactions 1, 21, 2729-2737 (1995)

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