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Key Documents

213292

Sigma-Aldrich

Sulfur

99.998% trace metals basis

Synonym(s):

sulfur powder

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About This Item

Empirical Formula (Hill Notation):
S
CAS Number:
Molecular Weight:
32.07
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23

vapor density

8.9 (vs air)

Quality Level

vapor pressure

1 mmHg ( 183.8 °C)
10 mmHg ( 246 °C)

Assay

99.998% trace metals basis

form

powder or flakes

autoignition temp.

450 °F

resistivity

2E23 μΩ-cm, 20°C

bp

444.7 °C (lit.)

mp

112.8 °C (rhombic) (lit.)
117-120 °C (lit.)
119.0 °C (monoclinic) (lit.)

density

2.07 g/mL at 25 °C

SMILES string

[S]

InChI

1S/S

InChI key

NINIDFKCEFEMDL-UHFFFAOYSA-N

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General description

Elemental sulfur exists in thirty different solid allotropes of which orthorhombic sulfur is the only thermodynamically stable form under normal temperature and pressure. It dissolves in a number of organic solvents and forms a large number of oxyacids. Sulfur is generally highly reactive; the S8 ring of elemental sulfur is easily broken by a number of nucleophilic reactants. The hydroxyl ions react with S at about 100oC.

Application

It finds applications in Li-S polymer batteries and as semiconductor-sensitizer layer CdS/CdSe/ZnS for solar cells.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Skin Irrit. 2

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Preparation and electrochemical properties of lithium-sulfur polymer batteries
Journal of Power Sources, 109(1), 89-97 (2002)
Effects of Nanosized Adsorbing Material on Electrochemical Properties of Sulfur Cathodes for LiOS Secondary Batteries
Journal of the Electrochemical Society, 151(6), A791-A795 (2004)
Multilayered semiconductor (CdS/CdSe/ZnS)-sensitized TiO2 mesoporous solar cells: all prepared by successive ionic layer adsorption and reaction processes.
Chemistry of Materials, 22(19), 5636-5643 (2010)
Lingli Huang et al.
Science advances, 6(47) (2020-11-20)
Low-dimensional materials usually exhibit mechanical properties from those of their bulk counterparts. Here, we show in two-dimensional (2D) rhenium disulfide (ReS2) that the fracture processes are dominated by a variety of previously unidentified phenomena, which are not present in bulk
Gulluzar Bastug et al.
The Journal of organic chemistry, 78(18), 9303-9308 (2013-08-14)
The newly prepared complex [Pd(IPr*(OMe))(cin)(Cl)] provides high catalytic activity for carbon-sulfur cross-coupling reactions. Nonactivated and deactivated aryl halides were successfully coupled with a large variety of aryl- and alkylthiols using this well-defined palladium N-heterocyclic carbene (NHC) complex.

Articles

From Form to Function: Molding Porous Materials in Three Dimensions by Colloidal Crystal Templating

Solvothermal synthesis is a method for preparing a variety of materials such as metals, semiconductors, ceramics, and polymers.

Spectral conversion for solar cells is an emerging concept in the field of photovoltaics, and it has the potential to increase significantly the efficiency of solar cells. Lanthanide ions are ideal candidates for spectral conversion, due to their high luminescence efficiencies and rich energy level structure that allows for great flexibility in the upconversion and downconversion of photons in a wide spectral region (NIR-VIS-UV).

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