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242969

Sigma-Aldrich

Sodium diphenylamine-4-sulfonate

ACS reagent

Synonym(s):

4-(Phenylamino)benzenesulfonic acid sodium salt, Diphenylamine-4-sulfonic acid sodium salt

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About This Item

Empirical Formula (Hill Notation):
C12H10NNaO3S
CAS Number:
6152-67-6
Molecular Weight:
271.27
EC Number:
228-165-6
MDL number:
MFCD00036468
UNSPSC Code:
12352100
PubChem Substance ID:
24854595
NACRES:
NA.21

grade

ACS reagent

Quality Level

200

technique(s)

titration: suitable

SMILES string

[Na+].[O-]S(=O)(=O)c1ccc(Nc2ccccc2)cc1

InChI

1S/C12H11NO3S.Na/c14-17(15,16)12-8-6-11(7-9-12)13-10-4-2-1-3-5-10;/h1-9,13H,(H,14,15,16);/q;+1/p-1

InChI key

DGXTZMPQSMIFEC-UHFFFAOYSA-M

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General description

Sodium diphenylamine-4-sulfonate has the ability to form colored complexes with metal ions. Hence it is commonly used as an indicator to estimate the concentration of metal ions. It is also an efficient quencher of electrochemiluminescence of tris (2, 2′-bipyridine)-ruthenium (II).

Application

Sodium diphenylamine-4-sulfonate may be used in the synthesis of poly-(aniline-co-N-(4-sulfophenyl)aniline via polymerization with aniline. It may also be used as a reductant in the synthesis of branched gold nanocrystals from gold(III) chloride trihydrate in the presence of polyethylene glycol. These nanocrystals have potential application as electrocatalysts.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL7321
MKCJ7679
MKCB0933V
MKBZ8262V
R048231/1V

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Quenching of the Electrochemiluminescence of Tris (2, 2'-bipyridine)-ruthenium (II) by Sodium Diphenylamine-4-sulfonate
Zhu Y, et al
Analytical Sciences, 25(6), 785-788 (2009)
Reaction products between sodium diphenyl-amine-4-sulfonate and hydrated LaCl3.
Machado LC, et al.
Journal of Thermal Analysis and Calorimetry, 75(2), 615-621 (2004)
The effects of several sulfonates on thermal and fire retardant properties of poly (methyl methacrylate) and polystyrene.
He J, et al.
Polymers For Advanced Technologies, 25(2), 160-167 (2014)
Synthesis and properties of novel water-soluble conducting polyaniline copolymers.
Nguyen MT, et al.
Macromolecules, 27(13), 3625-3631 (1994)
High-yield Synthesis of Branched Gold Nanocrystals by a Sodium Diphenylamine-4-Sulfonate Reduction Process in Polyethylene Glycol Aqueous Solution.
Liu Q, et al.
Chin. J. Chem., 28(4), 537-542 (2010)

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