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Key Documents

V1503

Sigma-Aldrich

Vinyl acetate

contains 3-20 ppm hydroquinone as inhibitor, ≥99%

Synonym(s):

VAc, Acetoxyethylene

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About This Item

Linear Formula:
CH3CO2CH=CH2
CAS Number:
Molecular Weight:
86.09
Beilstein:
1209327
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

3 (vs air)

vapor pressure

88 mmHg ( 20 °C)

Assay

≥99%

autoignition temp.

801 °F

contains

3-20 ppm hydroquinone as inhibitor

expl. lim.

13.4 %

refractive index

n20/D 1.395 (lit.)

bp

72-73 °C (lit.)

mp

−93 °C (lit.)

density

0.934 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(=O)OC=C

InChI

1S/C4H6O2/c1-3-6-4(2)5/h3H,1H2,2H3

InChI key

XTXRWKRVRITETP-UHFFFAOYSA-N

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Application

Vinyl acetate has been used as an acyl donor for enzyme-catalyzed acylation reactions.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Carc. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

17.6 °F - closed cup

Flash Point(C)

-8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Lipases efficiently stearate and cutinases acetylate the surface of arabinoxylan films.
Stepan AM
Journal of Biotechnology, 167(1), 16-23 (2013)
María Laura Lastra et al.
Colloids and surfaces. B, Biointerfaces, 196, 111322-111322 (2020-08-26)
Recent studies have shown the relevance of growing mesenchymal stem cells (MSCs) in three-dimensional environments with respect to the monolayer cell culture on an adherent substrate. In this sense, macroporous scaffolds and hydrogels have been used as three-dimensional (3D) supports.
Kinetic resolution of 4-chloro-2-(1-hydroxyalkyl) pyridines using Pseudomonas cepacia lipase.
Busto E
Nature Protocols, 1(4), 2061-2061 (2006)
Ping Xu et al.
Polymers, 11(2) (2019-04-10)
Hyperbranched polycaprolactone with controlled structure was synthesized by reversible addition-fragmentation chain transfer radical ring-opening polymerization along with self-condensed vinyl polymerization (SCVP) of 2-methylene-1,3-dioxepane (MDO). Vinyl 2-[(ethoxycarbonothioyl) sulfanyl] propanoate (ECTVP) was used as polymerizable chain transfer agent. Living polymerization behavior was
B Picquet-Varrault et al.
Environmental science & technology, 44(12), 4615-4621 (2010-05-25)
Vinyl acetate is widely used in industry. It has been classified as a high-production volume (HPV) chemical in the United States. To evaluate its impact on the environment and air quality, its atmospheric reactivity toward the three main tropospheric oxidants

Articles

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Protocols

RAFT (Reversible Addition-Fragmentation chain Transfer) is a form of living radical polymerization involving conventional free radical polymerization of a substituted monomer in the presence of a suitable chain transfer (RAFT) reagent.

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