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ALD00004

Sigma-Aldrich

Li-Yu t-Butyl Quinoline

95%

Synonym(s):

3,4-Dihydro-7-tert-butyl-2,5-dimethyl-2H-pyrano[2,3-b]quinoline

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About This Item

Empirical Formula (Hill Notation):
C18H23NO
Molecular Weight:
269.38
MDL number:
MFCD28016344
UNSPSC Code:
12352005
PubChem Substance ID:
329772510
NACRES:
NA.22

Assay

95%

form

solid

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

mp

202-207 °C

SMILES string

CC1=C2C(OC(C)CC2)=NC3=C1C=C(C(C)(C)C)C=C3

InChI

1S/C18H23NO/c1-11-6-8-14-12(2)15-10-13(18(3,4)5)7-9-16(15)19-17(14)20-11/h7,9-11H,6,8H2,1-5H3

InChI key

HGKGTNXPFXRVQB-UHFFFAOYSA-N

Application

Ligand is optimal for gamma C-H functionalization of aliphatic acids through Pd-catalyzed C-H activation. The Yu group has demonstrated a variety of transformations, such as olefination, carbonylation, and arylation.

Other Notes

Ligand-Enabled g-C–H Olefination and Carbonylation: Construction of b-Quaternary Carbon Centers

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCM7744
MKBR5585V

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