708496
Acetyl chloride solution
1 M in methylene chloride
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About This Item
Empirical Formula (Hill Notation):
C2H3ClO
CAS Number:
Molecular Weight:
78.50
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
form
liquid
Quality Level
concentration
1 M in methylene chloride
refractive index
n20/D 1.423
density
1.294 g/mL at 25 °C
SMILES string
CC(Cl)=O
InChI
1S/C2H3ClO/c1-2(3)4/h1H3
InChI key
WETWJCDKMRHUPV-UHFFFAOYSA-N
Application
Acetyl chloride (AcCl) can be used as:
- An acylating reagent to prepare useful key intermediates in organic synthesis.
- A reagent to convert oxathioacetals and dithioacetals into corresponding carbonyl compounds in the presence of sodium nitrite.
- An activating or acylating reagent in solid-phase organic synthesis.
- A reagent to prepare various alkyl and aryl tetrahydropyranyl ethers from corresponding alcohols.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Central nervous system
WGK
WGK 2
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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A highly efficient procedure for regeneration of carbonyl groups from their corresponding oxathioacetals and dithioacetals using sodium nitrite and acetyl chloride in dichloromethane
Khan AT, et al.
Synlett, 2003(03), 0377-0381 (2003)
New phenylfluorenyl based linkers for solid phase synthesis
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Tetrahedron Letters, 41(47), 9037-9042 (2000)
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