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Key Documents

703486

Sigma-Aldrich

sec-Butylmagnesium chloride lithium chloride complex solution

1.2 M in THF

Synonym(s):

2-Butylmagnesium chloride lithium chloride complex, Turbo Grignard

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About This Item

Linear Formula:
C4H9MgCl · LiCl
Molecular Weight:
159.27
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22

form

liquid

reaction suitability

reaction type: Grignard Reaction

concentration

1.2 M in THF
14 % (w/w)

density

0.973 g/mL at 25 °C

SMILES string

[Li]Cl.CCC(C)[Mg]Cl

InChI

1S/C4H9.2ClH.Li.Mg/c1-3-4-2;;;;/h3H,4H2,1-2H3;2*1H;;/q;;;2*+1/p-2

InChI key

ZMDHAYOBNXOYEU-UHFFFAOYSA-L

Application

Reagent for Selective Metalations

Used as:
  • Functionalization of cyclopentene derivatives

Legal Information

Product of Albemarle US Inc

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

-6.7 °F

Flash Point(C)

-21.5 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Articles

Selective Metalations using i-PrMgCl·LiCl and s-BuMgCl·LiCl

Transformative reagents for selective metalation, deprotonation and nucleophilic additions have allowed for unprecedented selective converstions to reactive intermediates within a molecule which contains sensative functionalities under mild reactions.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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