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680966

Sigma-Aldrich

2-Propylzinc bromide solution

0.5 M in THF

Synonym(s):

Isopropylzinc bromide

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About This Item

Linear Formula:
(CH3)2CHZnBr
CAS Number:
77047-87-1
Molecular Weight:
188.38
MDL number:
MFCD06200639
UNSPSC Code:
12352103
PubChem Substance ID:
24885605
NACRES:
NA.22

concentration

0.5 M in THF

density

0.963 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)[Zn]Br

InChI

1S/C3H7.BrH.Zn/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1

InChI key

IKQCKJSWVAERRG-UHFFFAOYSA-M

Application

2-Propylzinc bromide solution (0.5 M in THF) has been used as a reagent in a protocol for the nickel-catalyzed dehalogenation of organic halides.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH018,EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Nickel-catalyzed hydrodehalogenation of aryl halides
Weidauer Maik, et al.
Journal of Organometallic Chemistry, 729, 53-59 (2013)

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