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663301

Sigma-Aldrich

Trimethylaluminum

packaged for use in deposition systems

Synonym(s):

Aluminum trimethanide, TMA

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About This Item

Linear Formula:
(CH3)3Al
CAS Number:
75-24-1
Molecular Weight:
72.09
Beilstein:
3587197
EC Number:
200-853-0
MDL number:
MFCD00008252
UNSPSC Code:
12352103
PubChem Substance ID:
24884629
NACRES:
NA.23

vapor pressure

69.3 mmHg ( 60 °C)

Quality Level

100

description

heat of vaporization: ~41.9 kJ/mol (Dimer)

form

liquid

reaction suitability

core: aluminum

bp

125-126 °C (lit.)
127 °C/760 mmHg
20 °C/8 mmHg
56 °C/50 mmHg

mp

15 °C (lit.)

density

0.752 g/mL at 25 °C (lit.)

SMILES string

C[Al](C)C

InChI

1S/3CH3.Al/h3*1H3;

InChI key

JLTRXTDYQLMHGR-UHFFFAOYSA-N

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General description

Trimethylaluminum ismainly used in the industrial production of polyethylene and other syntheticpolymers, where it is used as a co-catalyst for the polymerization reaction. Itis also used as a precursor to produce inorganic aluminum compounds, includingalumina and various zeolites.

Application

Precursors Packaged for Depositions Systems
Trimethylaluminum can be used as:
  • A chemical vapor deposition precursor to fabricate PbSe quantum dot solids for optoelectronic devices.
  • An aluminum precursor for the flame synthesis of alumina nanofibers.
  • A reagent for efficient synthesis of allenes.

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H250,H260,H314

Hazard Classifications

Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1

Supplementary Hazards

EUH014

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

nwg

Flash Point(F)

No data available

Flash Point(C)

No data available

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL1265
SHBK4017
SHBJ5671
SHBG2107V
SHBH2969V

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ACS nano, 9(6), 5884-5892 (2015-05-15)
Lithium metal is considered to be the most promising anode for next-generation batteries due to its high energy density of 3840 mAh g(-1). However, the extreme reactivity of the Li surface can induce parasitic reactions with solvents, contamination, and shuttled
J L L Robinson et al.
Oncogene, 33(50), 5666-5674 (2013-12-03)
Castration-resistant prostate cancer (CRPC) continues to pose a significant clinical challenge with new generation second-line hormonal therapies affording limited improvement in disease outcome. As the androgen receptor (AR) remains a critical driver in CRPC, understanding the determinants of its transcriptional
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J Stebbing et al.
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