562289

3,5-Dichlorophenylmagnesium bromide solution

0.5 M in THF

• Linear Formula: Cl₂C₆H₃MgBr
• CAS Number: 82297-90-3
• Molecular Weight: 250.20
• MDL number: MFCD01319892
• UNSPSC Code: 12352103
• PubChem Substance ID: 24880024
• NACRES: NA.22

Properties

• reaction suitability: reaction type: Grignard Reaction
• Quality Level: 100
• concentration: 0.5 M in THF
• bp: 65 °C
• density: 0.972 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: Clc1cc(Cl)cc([Mg]Br)c1
• InChI: 1S/C6H3Cl2.BrH.Mg/c7-5-2-1-3-6(8)4-5;;/h2-4H;1H;/q;;+1/p-1
• InChI key: PWOVECVCCCTJFQ-UHFFFAOYSA-M

Description

Application

3,5-Dichlorophenylmagnesium bromide can be used:

• In one of the key synthetic steps for the preparation of non-alternant polycyclic hydrocarbon named indeno-benzophenalene.
• As a substrate in the synthesis of carboxylic esters by reacting with 2-methyl-4,6-pyrimidyl dicarbonates.
• As a substrate in the synthesis of aryl ketones by reacting with acid chlorides using bis[2-(N,N-dimethylamino)ethyl] ether ligand.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H302,H314,H335,H336,H351
• Precautionary Statements: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Target Organs: Central nervous system, Respiratory system
• Supplementary Hazards: EUH014,EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): -6.2 °F - closed cup
• Flash Point(C): -21.2 °C - closed cup