346160
Ethynylmagnesium chloride solution
0.5 M in THF
Synonym(s):
Chloromagnesium acetylide
About This Item
Recommended Products
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
density
0.921 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Cl[Mg]C#C
InChI
1S/C2H.ClH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1
InChI key
YEWNLGTVYUADOR-UHFFFAOYSA-M
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Application
- To synthesize 1-ethynyldeoxyribose derivatives which can further undergo Sonogashira coupling with various aryl, heteroaryl, and metallocenyl derivatives.
- In one of the key synthetic steps of substituted naphthostyrils.
- In the preparation of propargylic ester precursor for the synthesis of 1,3-dienylphosphonates.
recommended
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
-16.6 °F - closed cup
Flash Point(C)
-27 °C - closed cup
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