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241555

Sigma-Aldrich

Phosphorus triiodide

99%

Synonym(s):

Phosphorus(III) iodide

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About This Item

Linear Formula:
PI3
CAS Number:
Molecular Weight:
411.69
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99%

form

solid

mp

61 °C (lit.)

density

4.18 g/mL at 25 °C (lit.)

SMILES string

IP(I)I

InChI

1S/I3P/c1-4(2)3

InChI key

PZHNNJXWQYFUTD-UHFFFAOYSA-N

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General description

Phosphorus triiodide (PI3) is a trihalide of phosphorus that can be used as a deactivator and a deoxygenating agent.

Application

PI3 is used in the synthesis of black phosphate crystal, which can be used as a semiconducting material for optoelectronic applications. It is also a source of triiodide that can be utilized as a charge carrier in electrolytes for dye sensitized solar cells.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Understanding the growth of black phosphorus crystals.
Zhao M, et al.
CrystEngComm, 18(40), 7737-7744 (2016)
Photoelectrochemistry of mesoporous NiO electrodes in iodide/triiodide electrolytes.
Zhu H, et al.
The Journal of Physical Chemistry C, 111(47), 17455-17458 (2007)
Phosphorus tri-iodide (PI 3), a powerful deoxygenating agent.
Denis JN and Krief A
Journal of the Chemical Society. Chemical Communications, (12), 544-545 (1980)

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