Skip to Content
Merck
All Photos(4)

Key Documents

View All Documentation

151947

Sigma-Aldrich

Methanol-d4

≥99.8 atom % D

Synonym(s):

Methyl-d3 alcohol d, Tetradeuteromethanol

Sign Into View Organizational & Contract Pricing
All Photos(4)

About This Item

Linear Formula:
CD3OD
CAS Number:
811-98-3
Molecular Weight:
36.07
Beilstein:
1733278
EC Number:
212-378-6
MDL number:
MFCD00044637
UNSPSC Code:
12352104
PubChem Substance ID:
24849183
NACRES:
NA.21

isotopic purity

≥99.8 atom % D

Quality Level

200

Assay

≥99% (CP)

form

liquid

expl. lim.

5.5-36.5 % (lit.)

technique(s)

HPLC: suitable
NMR: suitable

impurities

≤0.025% water

refractive index

n20/D 1.326 (lit.)

bp

65.4 °C (lit.)

mp

-99 °C (lit.)

density

0.888 g/mL at 25 °C (lit.)

format

neat

SMILES string

[2H]OC([2H])([2H])[2H]

InChI

1S/CH4O/c1-2/h2H,1H3/i1D3,2D

InChI key

OKKJLVBELUTLKV-MZCSYVLQSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Methanol-d4 may have been used as solvent in the nuclear magnetic resonance spectrum analysis for:
  • characterizing phenolic compounds separated from olive oil using high performance liquid chromatography.
  • vanillic acid and 4-hydroxy-3-methoxystyrene formed via biotransformation of Rhodotorula rubra.

Recommended products

Check out ChemisTwin®, our brand new online portal for identity confirmation and quantification of NMR spectra. Learn more or reach out to us for a free trial.

accessory

Product No.
Description
Pricing

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Target Organs

Eyes,Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

49.5 °F - closed cup

Flash Point(C)

9.7 °C - closed cup

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MBBD3368
MBBD3316
MBBD3139
SHBN1521
MBBD3031

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Simple and Hydrolyzable Compounds in Virgin Olive Oil. 3.
Spectroscopic Characterizations of the Secoiridoid Derivatives
Montedoro G, et al.
Journal of Agricultural and Food Chemistry, 41, 2228-2234 (1993)
Mechanisms of ferulic acid conversions to vanillic acid and guaiacol by Rhodotorula rubra
Huang Z, et al.
The Journal of Biological Chemistry, 268(32), 23954-23958 (1993)
Eric M Rosenberg et al.
Cell chemical biology, 26(5), 662-673 (2019-03-05)
The G protein-coupled receptor (GPCR) CXCR4 is a co-receptor for HIV and is involved in cancers and autoimmune diseases. We characterized five purine or quinazoline core polyamine pharmacophores used for targeting CXCR4 dysregulation in diseases. All were neutral antagonists for
Cheng-Kun Lin et al.
Organic & biomolecular chemistry, 13(7), 2100-2107 (2014-12-20)
A straightforward synthesis of novel, 2-heterocyclyl polyhydroxylated pyrrolidines is described. Stereocontrolled additions of nucleophiles to cyclic nitrones generated the corresponding 2,3-trans adducts, allowing the synthesis of the corresponding pyrrolidines via key intermediates bearing an alkyne and a nitrile oxide. Three
Jon Kapla et al.
Physical chemistry chemical physics : PCCP, 17(34), 22438-22447 (2015-08-08)
The disaccharide trehalose (TRH) strongly affects the physical properties of lipid bilayers. We investigate interactions between lipid membranes formed by 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) and TRH using NMR spectroscopy and molecular dynamics (MD) computer simulations. We compare dipolar couplings derived from DMPC/TRH
View All Related Papers

Articles

NMR Deuterated Solvent Properties Reference Chart

Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.

Related Content

Nuclear Magnetic Resonance (NMR)

NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.

Nuclear Magnetic Resonance (NMR)

NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.

Nuclear Magnetic Resonance (NMR)

NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.

Nuclear Magnetic Resonance (NMR)

NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service