118559

1,5-Hexadien-3-ol

• Linear Formula: H₂C=CHCH₂CH(OH)CH=CH₂
• CAS Number: 924-41-4
• Molecular Weight: 98.14
• EC Number: 213-102-7
• MDL number: MFCD00008662
• UNSPSC Code: 12352100
• PubChem Substance ID: 24847376
• NACRES: NA.22

Properties

• refractive index: n20/D 1.448 (lit.)
• density: 0.878 g/mL at 25 °C (lit.)
• functional group: allyl; hydroxyl
• SMILES string: OC(CC=C)C=C
• InChI: 1S/C6H10O/c1-3-5-6(7)4-2/h3-4,6-7H,1-2,5H2
• InChI key: SZYLTIUVWARXOO-UHFFFAOYSA-N

Description

General description

1,5-Hexadien-3-ol is the starting reagent for the enantioselective synthesis of (+)-rogioloxepane A. It undergoes Sharpless kinetic resolution and ring-closing metathesis to yield nine membered oxocene.

Application

1,5-Hexadien-3-ol was used in the synthesis of (+)-obtusenyne.

Safety Information

• Pictograms: GHS02
• Signal Word: Warning
• Hazard Statements: H226
• Precautionary Statements: P210 - P233 - P240 - P241 - P242 - P243
• Hazard Classifications: Flam. Liq. 3
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 84.2 °F - closed cup
• Flash Point(C): 29 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves