242780
Sulfamic acid
reagent grade, 98%
Synonym(s):
Amidosulfonic acid
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About This Item
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grade
reagent grade
Quality Level
Assay
98%
form
powder or crystals
mp
215-225 °C (dec.) (lit.)
solubility
water: 213 g/L at 20 °C
water: 470 g/L at 80 °C
density
2.151 g/cm3 at 25 °C
SMILES string
NS(O)(=O)=O
InChI
1S/H3NO3S/c1-5(2,3)4/h(H3,1,2,3,4)
InChI key
IIACRCGMVDHOTQ-UHFFFAOYSA-N
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General description
Sulfamic acid (H2NSO3H) is a strong inorganic acid. It exists in zwitterionic form and neutral forms. Zwitterionic form is more stable than neutral form.
The ability of sulfamic acid/zinc powder to reduce nitrate to nitrogen gas under acidic condition has been utilized to denitrify nitrate-rich wastewater.
The ability of sulfamic acid/zinc powder to reduce nitrate to nitrogen gas under acidic condition has been utilized to denitrify nitrate-rich wastewater.
Application
Sulfamic acid (H2NSO3H) may be used in the following studies:
- As a catalyst in the synthesis of aryl-14H-dibenzo[a.j]xanthenes.
- As a green catalyst for the liquid Beckmann rearrangement of ketoxime in dried acetonitrile.
- As a nitrogen source as well as an in situ activator of hydroxy groups in the direct iridium-catalyzed synthesis of primary allylic amines from allylic alcohols.
- Synthesis of polysubstituted quinolones.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Denitrification of simulated nitrate-rich wastewater using sulfamic acid and zinc scrap.
Chemical Papers, 65(4), 437-446 (2011)
Sulfamic acid as a cost-effective and recyclable catalyst for liquid Beckmann rearrangement, a green process to produce amides from ketoximes without waste.
Tetrahedron Letters, 45(17), 3369-3372 (2004)
Sulfamic acid: an efficient, cost-effective and recyclable solid acid catalyst for the Friedlander quinoline synthesis.
Tetrahedron Letters, 46(42, 7249-7253 (2005)
Iridium-catalyzed synthesis of primary allylic amines from allylic alcohols: sulfamic acid as ammonia equivalent.
Angewandte Chemie (International ed. in English), 46(17), 3139-3143 (2007-03-14)
Sulfamic acid: a novel and efficient catalyst for the synthesis of aryl-14H-dibenzo [a. j] xanthenes under conventional heating and microwave irradiation.
Tetrahedron Letters, 46(50), 8691-8693 (2005)
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