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798835

Sigma-Aldrich

[Ru(phd)3](PF6)2

Synonym(s):

Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)

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About This Item

Empirical Formula (Hill Notation):
C36H18F12N6O6P2Ru
CAS Number:
184023-77-6
Molecular Weight:
1021.56
UNSPSC Code:
12352300
PubChem Substance ID:
329768673
NACRES:
NA.22

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

SMILES string

F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]

InChI

1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2

InChI key

LGAOGZFZNIEFHF-UHFFFAOYSA-N

Application

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)3](PF6)2 is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

Legal Information

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

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