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227730

Sigma-Aldrich

Silver hexafluoroantimonate(V)

98%

Synonym(s):

Silver hexafluoroantimony, Silver hexafluorostiboranuide

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About This Item

Linear Formula:
AgSbF6
CAS Number:
Molecular Weight:
343.62
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

98%

form

powder

reaction suitability

reagent type: catalyst
core: silver

SMILES string

[Ag+].F[Sb-](F)(F)(F)(F)F

InChI

1S/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6

InChI key

GSXFODUDOAXUBF-UHFFFAOYSA-H

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Application

Generates stable cation radical salts and is used as an acidic catalyst in epoxide opening reactions and sulfenylation reactions. Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles.
Jie Huang et al.
Journal of the American Chemical Society, 129(26), 8060-8061 (2007-06-09)
The Journal of Organic Chemistry, 57, 6178-6178 (1992)
Chemistry Letters (Jpn), 1-1 (1993)
Chemistry Letters (Jpn), 1901-1901 (1992)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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