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Ligand Substituents Govern the Efficiency and Mechanistic Path of Hydrogen Production with [Cp*Rh] Catalysts.

Ligand Substituents Govern the Efficiency and Mechanistic Path of Hydrogen Production with [Cp*Rh] Catalysts.

ChemSusChem (2017-10-13)

Wade C Henke, Davide Lionetti, William N G Moore, Julie A Hopkins, Victor W Day, James D Blakemore

摘要

We demonstrate that [Cp*Rh] complexes bearing substituted 2,2'-bipyridyl ligands are effective hydrogen evolution catalysts (Cp*=η

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Sigma-Aldrich

二茂铁, 98%

Sigma-Aldrich

4-叔丁基吡啶, 98%

Sigma-Aldrich

2-氯-4-(三氟甲基)吡啶, 97%