Total synthesis of aspercyclides A and B via intramolecular oxidative diaryl ether formation.

Total synthesis of aspercyclides A and B via intramolecular oxidative diaryl ether formation.

Organic letters (2012-08-09)

Tatsuya Yoshino, Itaru Sato, Masahiro Hirama

摘要

A highly efficient total synthesis of the 11-membered cyclic aspercyclides A (1) and B (2) has been achieved by chemo- and regioselective intramolecular oxidative C-O bond formation from differently substituted diphenols.

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673811

Sigma-Aldrich

二乙醚, anhydrous, ACS reagent, ≥99.0%, contains BHT as inhibitor

309966

Sigma-Aldrich

二乙醚, suitable for HPLC, ≥99.9%, inhibitor-free

346136

Sigma-Aldrich

二乙醚, ACS reagent, anhydrous, ≥99.0%, contains BHT as inhibitor

296082

Sigma-Aldrich

二乙醚, contains 1 ppm BHT as inhibitor, anhydrous, ≥99.7%

32203

Sigma-Aldrich

二乙醚, contains BHT as inhibitor, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8% (GC)

09-1810

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二乙醚, SAJ first grade, ≥99.0%

676845

Sigma-Aldrich

二乙醚, ACS reagent, ≥98.0%, contains ≤2% ethanol and ≤10ppm BHT as inhibitor

91238

Supelco

二乙醚, analytical standard

24004

Sigma-Aldrich

二乙醚, puriss., contains ~5 mg/L 2,6-di-tert.-butyl-4-methylphenol as stabilizer, meets analytical specification of Ph. Eur., BP, ≥99.5% (GC)

346144

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二乙醚, reagent grade, ≥98%, contains ≤2% ethanol and ≤10ppm BHT as inhibitor

09-1800

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二乙醚, JIS special grade, ≥99.5%

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09-1830

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二乙醚, JIS 300, ≥99.5%, for residue analysis

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二乙醚, JIS 1000, ≥99.5%, for residue analysis

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