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Merck
  • An unusual addition reaction for constructing a novel pH-controlled fluorescence switch.

An unusual addition reaction for constructing a novel pH-controlled fluorescence switch.

Organic letters (2010-12-15)
Chunjie Zhou, Yongjun Li, Yingjie Zhao, Jianhong Zhang, Wenlong Yang, Yuliang Li
摘要

A pH-controlled fluorescence switch based on a core-substituted naphthalenediimide compound (NDI-DBU) was constructed. The novel pentacyclic compound (NDI-DBU) was derived from naphthalenediimide (NDI) and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in only one synthetic operation, catalysized by CuI.

材料
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产品描述

Sigma-Aldrich
1,8-二氮杂双环[5.4.0]十一碳-7-烯, 98%
Sigma-Aldrich
1,8-二氮杂双环[5.4.0]十一碳-7-烯, puriss., ≥99.0% (GC)