- Development of highly active and selective novel Pd based acetoxylation catalysts and prevention of catalyst deactivation by Bi modification.
Development of highly active and selective novel Pd based acetoxylation catalysts and prevention of catalyst deactivation by Bi modification.
Chemical communications (Cambridge, England) (2004-10-30)
A Benhmid, K V Narayana, A Martin, B Lucke, M-M Pohl
PMID15514793
摘要
A first approach to successful prevention of catalyst deactivation while simultaneously achieving extremely high selectivity of benzyl acetate (> or = 95%) at significantly high toluene conversion (> 70%) by gas phase acetoxylation over novel Pd-Sb-Bi/TiO2 catalysts.