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32499

Supelco

Dinotefuran

PESTANAL®, analytical standard

Synonym(s):

(RS)-N-Methyl-N′-nitro-N″-[(tetrahydro-3-furanyl)methyl]guanidine

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About This Item

Empirical Formula (Hill Notation):
C7H14N4O3
CAS Number:
Molecular Weight:
202.21
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CN\C(N[N+]([O-])=O)=N/CC1CCOC1

InChI

1S/C7H14N4O3/c1-8-7(10-11(12)13)9-4-6-2-3-14-5-6/h6H,2-5H2,1H3,(H2,8,9,10)

InChI key

YKBZOVFACRVRJN-UHFFFAOYSA-N

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General description

Dinotefuran, a new neonicotinoid insecticide has low mammalian toxicity and great insecticidal activity against a broad range of pests.
Find more information here: Neonicotinoids

Application

Dinotefuran has been used as a standard for the determination of neonicotinoid insecticide residues in dietary bee pollen and melon samples by HPLC–MS/MS and high performance liquid chromatography coupled with ultraviolet detector (HPLC-UVD), respectively.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Certificates of Analysis (COA)

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Eiki Watanabe et al.
Talanta, 84(4), 1107-1111 (2011-05-03)
The analytical performance of a kit-based enzyme-linked immunosorbent assay (ELISA) for the determination of a neonicotinoid insecticide dinotefuran residue in rice samples is addressed. The sensitivity (I(50) value) was 5.4 ng/mL, with the limit of detection, 0.6 ng/mL and the
XiaoBin Shi et al.
Pest management science, 67(12), 1528-1533 (2011-06-30)
Imidacloprid has been a major neonicotinoid insecticide for controlling Aphis gossypii (Glover) (Homoptera: Aphididae) and other piercing-sucking pests. However, the resistance to imidacloprid has been recorded in many target insects. At the same time, cross-resistance of imidacloprid and other insecticides
Raymond A Cloyd et al.
Pest management science, 67(1), 3-9 (2010-08-20)
The neonicotinoid insecticides imidacloprid, acetamiprid, dinotefuran, thiamethoxam and clothianidin are commonly used in greenhouses and/or interiorscapes (plant interiorscapes and conservatories) to manage a wide range of plant-feeding insects such as aphids, mealybugs and whiteflies. However, these systemic insecticides may also
The discovery of dinotefuran: a novel neonicotinoid.
Wakita T, et al.
Pest Management Science, 59(9), 1016-1022 (2003)
Frank J Byrne et al.
Pest management science, 63(9), 860-866 (2007-07-27)
The efficacies of four systemic neonicotinoid insecticides applied to potted avocado trees at manufacturer-recommended rates were assessed against the avocado thrips, Scirtothrips perseae Nakahara. At the time of treatment, fully expanded first-flush young leaves were tagged for identification, and a

Articles

Determination of Neonicotinoids in Honey using a Chromolith RP-18 HPLC column and UV Detection

Protocols

Honey bee exposure to neonicotinoid pesticides could contribute to colony collapse disorder (CCD). This application utilizes QuEChERS Extraction and LC-MS Analysis.

LC/MS/MS Analysis of Neonicotinoid Pesticides in Dandelion Blossoms on Ascentis® Express C18 after Dispersive SPE (QuEChERS) using Supel™ QuE

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

On Friday, April 27, 2018, the European Union decided to ban the use of three neonicotinoid insecticides from use on field crops, having deemed them dangerous to bees. This application demonstrates the analysis of these banned compounds and others from dandelion blossoms using QuEChERS and LC-MS.

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