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13-0730

Sigma-Aldrich

Hexamethylenediamine

SAJ first grade, ≥98.0%

Synonym(s):

1,6-Diaminohexane, 1,6-Hexanediamine, HMDA

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About This Item

Linear Formula:
NH2(CH2)6NH2
CAS Number:
124-09-4
Molecular Weight:
116.20
Beilstein:
1098307
EC Number:
204-679-6
MDL number:
MFCD00008243
UNSPSC Code:
12352116
PubChem Substance ID:
329749993

grade

SAJ first grade

vapor density

4 (vs air)

Assay

≥98.0%

form

solid

expl. lim.

6.3 %

availability

available only in Japan

refractive index

n20/D 1.439 (lit.)

pH

12.4 (25 °C, 100 g/L)

mp

42-45 °C (lit.)

density

0.89 g/mL at 25 °C (lit.)

SMILES string

NCCCCCCN

InChI

1S/C6H16N2/c7-5-3-1-2-4-6-8/h1-8H2

InChI key

NAQMVNRVTILPCV-UHFFFAOYSA-N

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Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312,H314,H335

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

176.0 °F - closed cup

Flash Point(C)

80 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Richard F G Fröhlich et al.
Carbohydrate research, 346(12), 1592-1598 (2011-06-08)
Two simple and reliably accessible intermediates, N-carboxypentyl- and N-aminohexyl-1-deoxy-D-galactonojirimycin were employed for the synthesis of a set of terminally N-dansyl substituted derivatives. Reaction of the terminal carboxylic acid of N-carboxypentyl-1-deoxy-D-galactonojirimycin with N-dansyl-1,6-diaminohexane provided the chain-extended fluorescent derivative. Employing bis(6-dansylaminohexyl)amine, the
Junseok Yeom et al.
Bioconjugate chemistry, 21(2), 240-247 (2010-01-19)
A novel, biocompatible, and nontoxic dermal filler using hyaluronic acid (HA) hydrogels was successfully developed for tissue augmentation applications. Instead of using highly reactive cross-linkers such as divinyl sulfone (DVS) for Hylaform, 1,4-butanediol diglycidyl ether (BDDE) for Restylane, and 1,2,7,8-diepoxyoctane
Zhiming Zhang et al.
Inorganic chemistry, 47(17), 7615-7622 (2008-08-06)
The reaction between K 12[H 2P 2W 12O 48] and CuCl 2 in a NaCl aqueous solution assisted with organoamines (1,2-ethylenediamine (en), 1,6-hexamethylene diamine (hn), or both) leads to the isolation of three compounds: K 4Na 10[alpha 1-CuP 2W 17O
Wei-Chiang Chen et al.
ACS applied materials & interfaces, 1(8), 1821-1826 (2010-04-02)
Solvent microenvironments are formed around individual single-walled carbon nanotubes (SWNTs) by mixing SWNT suspensions with water-immiscible organic solvents. These microenvironments are used to encapsulate the SWNTs with the monomer sebacoyl chloride. Hexamethylene diamine is then injected into the aqueous phase
Sheila L Flack et al.
The Annals of occupational hygiene, 54(1), 41-54 (2009-10-07)
Quantification of amines in biological samples is important for evaluating occupational exposure to diisocyanates. In this study, we describe the quantification of 1,6-hexamethylene diamine (HDA) levels in hydrolyzed plasma of 46 spray painters applying 1,6-hexamethylene diisocyanate (HDI)-containing paint in vehicle
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