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923524

Sigma-Aldrich

(tBuMPhos)PdCl2

Synonym(s):

1-Diadamantylphosphino-1′-di-tert-butylphosphinoferrocene palladium dichloride

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About This Item

Empirical Formula (Hill Notation):
C38H56Cl2FeP2Pd
Molecular Weight:
807.97
UNSPSC Code:
12352200
NACRES:
NA.21

form

powder

Quality Level

100

Application

(tBuMPhos)PdCl2 is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing CyMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings

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Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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