Skip to Content
Merck
All Photos(1)

Key Documents

809330

Sigma-Aldrich

Fe/ppm Pd for nitro group reductions

Sign Into View Organizational & Contract Pricing


About This Item

MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22

form

solid

Quality Level

composition

FeCl2 (372870), 23.3-27.4 wt. %
MgCl2 (M8266), 15.3-18.8 wt. %
Pd (203939), <0.3 wt. %
THF (186562), 53.5-61.6 wt. %

reaction suitability

core: iron
reagent type: catalyst

storage temp.

2-8°C

Application

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

Caution

Handle under nitrogen and store under argon in refrigerator.

related product

Product No.
Description
Pricing

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

1.4 °F

Flash Point(C)

-17 °C


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

New surfactants for chemistry in water.
Krause N
Current opinion in green and sustainable chemistry., 7, 18-22 (2017)
Switching from organic solvents to water at an industrial scale.
Parmentier M, et al.
Current opinion in green and sustainable chemistry., 7, 13-17 (2017)
When Does Organic Chemistry Follow Nature?s Lead and ?Make the Switch?.
Lipshutz B H
The Journal of Organic Chemistry, 82(6), 2806-2816 (2017)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service