798835

[Ru(phd)₃](PF₆)₂

• Synonym(s): Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)
• Empirical Formula (Hill Notation): C₃₆H₁₈F₁₂N₆O₆P₂Ru
• CAS Number: 184023-77-6
• Molecular Weight: 1021.56
• UNSPSC Code: 12352202
• PubChem Substance ID: 329768673
• NACRES: NA.22

Properties

• form: powder
• reaction suitability: core: ruthenium; reagent type: catalyst
• SMILES string: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
• InChI: 1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2
• InChI key: LGAOGZFZNIEFHF-UHFFFAOYSA-N

Description

Application

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)₃](PF₆)₂ is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

Legal Information

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

Safety Information

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable