459690
4-Benzyloxy-1-butanol
97%
Synonym(s):
Tetramethylene glycol monobenzyl ether
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Assay
97%
refractive index
n20/D 1.513 (lit.)
bp
216-256 °C (lit.)
density
1.025 g/mL at 25 °C (lit.)
SMILES string
OCCCCOCc1ccccc1
InChI
1S/C11H16O2/c12-8-4-5-9-13-10-11-6-2-1-3-7-11/h1-3,6-7,12H,4-5,8-10H2
InChI key
TYROJDFHUXSBHC-UHFFFAOYSA-N
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General description
4-Benzyloxy-1-butanol can be prepared starting from butane-1,4-diol.
Application
4-Benzyloxy-1-butanol may be used for the preparation of ethyl 6-benzyloxy-2-hexenoate, via Swern oxidation and Wadsworth-Emmons olefination. It may be used as starting reagent for the synthesis of 4-(benzyloxy)butanal.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
228.2 °F - closed cup
Flash Point(C)
109 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Improved preparation of ?-hydroxy-a-amino acids: direct formation of sulfates by sulfuryl chloride.
Tetrahedron Asymmetry, 16(23), 3908-3912 (2005)
The syntheses of tricyclic analogues of O 6-methylguanine.
Organic & Biomolecular Chemistry, 1(23), 4166-4172 (2003)
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