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Sigma-Aldrich

1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

95%

Synonym(s):

BNDHP

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About This Item

Empirical Formula (Hill Notation):
C20H13O4P
CAS Number:
35193-63-6
Molecular Weight:
348.29
EC Number:
252-425-8
MDL number:
MFCD00010045
UNSPSC Code:
12352005
PubChem Substance ID:
24857622
NACRES:
NA.22

Assay

95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

SMILES string

OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45

InChI

1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)

InChI key

JEHUZVBIUCAMRZ-UHFFFAOYSA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Ulrich Schmitt et al.
Electrophoresis, 25(16), 2801-2807 (2004-09-08)
Comparative enantioseparation of the enantiomers of 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate was performed with cyclodextrin (CD)-modified capillary electrophoresis (CE). Two single isomers, beta-CD, heptakis(2,3,6-tri-O-methyl)-beta-CD (TM-beta-CD), and heptakis(2,6-di-O-methyl)-beta-CD (DM-beta-CD) of 98% purity as well as heptakis(2,3-di-O-acetyl)-beta-CD were used and compared in terms of
Ioannis J Stavrou et al.
Electrophoresis, 34(4), 524-530 (2012-12-05)
In this study, the applicability of a chiral ionic liquid (CIL) as the sole chiral selector in CE was investigated for the first time. In particular, five amino acid ester-based CILs were synthesized and used as additives in the BGE
Stephanie A Kingsbury et al.
Magnetic resonance in chemistry : MRC, 48(3), 184-191 (2010-01-06)
NMR spectroscopy was used to characterize the binding of the chiral compound 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate (BNP) to five molecular micelles with chiral dipeptide headgroups. Molecular micelles have covalent linkages between the surfactant monomers and are used as chiral mobile phase
Fluorescence anisotropy as a measure of chiral recognition.
M E McCarroll et al.
Journal of the American Chemical Society, 123(13), 3173-3174 (2001-07-18)
Christine M Hebling et al.
Langmuir : the ACS journal of surfaces and colloids, 24(24), 13866-13874 (2008-12-05)
Bile salt micelles can be employed as a pseudostationary phase in micellar electrokinetic capillary chromatography (MEKC) separations of chiral analytes. To improve MEKC separations of chiral analytes, a molecular level understanding of micelle aggregation in the presence of analyte is
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