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252670

Sigma-Aldrich

Chlorotriisopropoxytitanium(IV) solution

1.0 M in hexanes

Synonym(s):

Chlorotitanium(IV) triisopropoxide, Propan-2-olate titanium(4+) chloride, Titanium(IV) chloride triisopropoxide

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About This Item

Linear Formula:
[(CH3)2CHO]3TiCl
CAS Number:
20717-86-6
Molecular Weight:
260.58
MDL number:
MFCD00009861
UNSPSC Code:
12352103
PubChem Substance ID:
24855230
NACRES:
NA.23

form

solution

Quality Level

100

reaction suitability

core: titanium
reagent type: catalyst

concentration

1.0 M in hexanes

density

0.775 g/mL at 25 °C

SMILES string

CC(C)O[Ti](Cl)(OC(C)C)OC(C)C

InChI

1S/3C3H7O.ClH.Ti/c3*1-3(2)4;;/h3*3H,1-2H3;1H;/q3*-1;;+4/p-1

InChI key

IFMWVBVPVXRZHE-UHFFFAOYSA-M

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Application

Chlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes.

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

71.6 °F

Flash Point(C)

22 °C

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Certificates of Analysis (COA)

Lot/Batch Number
SHBN8925
SHBH6051
SHBG8881V
SHBF7155V
SHBD7670V

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The preparation and properties of some σ-alkyl and σ-aryl derivatives of titanium.
Rausch MD and Gordon HB
Journal of Organometallic Chemistry, 74(1), 85-90 (1974)
Stereoselective synthesis of 3, 7-diarylaminocholestanes by titanium-mediated reductive amination.
Ahmad Md Wasi and Kim HS
Steroids, 88, 53-59 (2014)
Mesoporous Oxides and Their Applications to Hydrogen Storage
Hunt AJ, et al.
Material Matters, 4(2) null

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