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128333

Sigma-Aldrich

Fluorene

98%

Synonym(s):

2,2′-Methylenebiphenyl, Diphenylenemethane

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About This Item

Empirical Formula (Hill Notation):
C13H10
CAS Number:
Molecular Weight:
166.22
Beilstein:
1363491
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

chunks
crystalline powder
crystals
powder
solid

bp

298 °C (lit.)

mp

111-114 °C (lit.)

SMILES string

C1c2ccccc2-c3ccccc13

InChI

1S/C13H10/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)12/h1-8H,9H2

InChI key

NIHNNTQXNPWCJQ-UHFFFAOYSA-N

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General description

Fluorene is a rigid, planar polycyclic aromatic hydrocarbon. White crystals of fluorene have violet fluorescence, from which its name derives. It is used as a precursor to other fluorene compounds. Fluorene is used as a chemical intermediate in the formation of polyradicals for resins as well as the manufacture of resinous products and dyes.

Application

Fluorene was used study the extraction of specific, semiconducting single-wall carbon nanotubes (SWCNTs).

Features and Benefits

As a monomer, fluorene exhibits significant solubility while maintaining a high degree of delocalization.

Pictograms

Environment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

303.8 °F - closed cup

Flash Point(C)

151.0 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Masayoshi Tange et al.
Nanoscale, 6(1), 248-254 (2013-11-05)
To understand how fluorene-based polymers selectively extract specific semiconducting single-wall carbon nanotubes (SWCNTs), we compared the optical transitions of SWCNTs wrapped with poly(9,9-dioctylfluorene-alt-pyridine) (PFOPy), i.e., structure-selective polymers, with those wrapped with poly(9,9-di-n-dodecylfluorene) (PFD), i.e., non-selective polymers, in organic solvents by
Zhengcai Guo et al.
Bioelectrochemistry (Amsterdam, Netherlands), 135, 107552-107552 (2020-06-12)
Developing a cost-effective and simple micro-analysis tool has long been an important objective in the toxicological detection of fluorene. In this study, a disposable paper-based micro-analysis device (μ-PAD) was designed using graphite doped with multi-walled carbon nanotubes (MWCNTs) to hand
Willian G Birolli et al.
Marine pollution bulletin, 129(2), 525-533 (2017-10-23)
The biodegradation of polycyclic aromatic hydrocarbons (PAHs) by marine-derived fungi was reported in this work. Marine-derived fungi (Trichoderma harzianum CBMAI 1677, Cladosporium sp. CBMAI 1237, Aspergillus sydowii CBMAI 935, Penicillium citrinum CBMAI 1186 and Mucor racemosus CBMAI 847) biodegraded anthracene
Qianling Cui et al.
ACS applied materials & interfaces, 5(1), 213-219 (2012-12-15)
In the present work, a facile one-pot method is designed to fabricate a core-shell fluorescent nanoparticle (NP) for cellular imaging based on a new cationic conjugated polymer, poly[9,9'-bis(6,6'-(N,N,N-trimethylaminium)fluorene-2,7-ylenevinylene-co-alt-2,5-dicyano-1,4-phenylene] (PFVCN). Gold nanoflowers (AuNFs) are prepared by a seedless method, in which
C Grazia Bezzu et al.
Advanced materials (Deerfield Beach, Fla.), 24(44), 5930-5933 (2012-09-11)
A highly gas-permeable polymer with enhanced selectivities is prepared using spirobifluorene as the main structural unit. The greater rigidity of this polymer of intrinsic microporosity (PIM-SBF) facilitates gas permeability data that lie above the 2008 Robeson upper bound, which is

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