CRM38373

Rimsulfuron

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Synonym(s): 1-(4,6-Dimethoxy-2-pyrimidinyl)-3-[3-(ethylsulfonyl)-2-pyridylsulfonyl]urea
• Empirical Formula (Hill Notation): C₁₄H₁₇N₅O₇S₂
• CAS Number: 122931-48-0
• Molecular Weight: 431.44
• Beilstein: 7501778
• MDL number: MFCD01632305
• UNSPSC Code: 41116107

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• storage temp.: −20°C
• SMILES string: CCS(=O)(=O)c1cccnc1S(=O)(=O)NC(=O)Nc2nc(OC)cc(OC)n2
• InChI: 1S/C14H17N5O7S2/c1-4-27(21,22)9-6-5-7-15-12(9)28(23,24)19-14(20)18-13-16-10(25-2)8-11(17-13)26-3/h5-8H,4H2,1-3H3,(H2,16,17,18,19,20)
• InChI key: MEFOUWRMVYJCQC-UHFFFAOYSA-N

Description

General description

This reference material (RM) is produced and certified in accordance with ISO/IEC 17025. This RM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

Rimsulfuron is a sulfonylurea herbicide, used for postemergence use in many crops like potatoes, maize, tomatoes, etc. to control grasses and some broadleaf weeds. Like other sulfonylureas, the site of action of rimsulfuron is acetolactate synthase (ALS)— an enzyme for the biosynthesis of branched-chain amino acids .

As per Regulation (EC) No 1107/2009, repealing the directive 91/414/EEC, rimsulfuron is approved for use in the European Union(EU). A maximum residue limit (MRL) of 0.01-0.02 mg/kg is applicable for the presence of rimsulfuron in fresh/frozen fruits, and tree nuts, in accordance with Regulation Reg. (EU) 617/2014.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.

The certified reference material(CRM) rimsulfuron may find the following uses:

• To study the basis of the selectivity of the herbicide rimsulfuron in maize
• Quantify leaching of the widely used low-dosage sulfonylurea herbicides rimsulfuron and its primary degradation products
• Residue analysis of a sulfonylurea herbicide, rimsulfuron, and its dissipation in soil and potato plants under field conditions using ultra-performance liquid chromatography coupled with tandem mass spectrometry (UPLC-MS/MS)
• Analysis of electrochemical behavior and determination of rimsulfuron herbicide by square wave voltammetry
• Simultaneous determination of rimsulfuron and haloxyfop-p-methyl and its metabolite haloxyfop in tobacco leaf by liquid chromatography with tandem mass spectrometry (LC-MS/MS)

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable