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62574

Sigma-Aldrich

Lithium nitrate

BioUltra, ≥99.0% (calc. on dried substances, T)

Synonym(s):

LiNO3, Lithium salt of nitric acid

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About This Item

Linear Formula:
LiNO3
CAS Number:
7790-69-4
Molecular Weight:
68.95
EC Number:
232-218-9
MDL number:
MFCD00011094
UNSPSC Code:
12352302
PubChem Substance ID:
57651899
NACRES:
NA.25

product line

BioUltra

Quality Level

200

Assay

≥99.0% (calc. on dried substances, T)

form

solid

impurities

insoluble matter, passes filter test

loss

≤2% loss on drying, 110 °C

pH

6-9 (25 °C, 1 M in H2O)

mp

264 °C (lit.)

solubility

H2O: 1 M at 20 °C, clear, colorless

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤100 mg/kg

cation traces

Al: ≤10 mg/kg
As: ≤0.1 mg/kg
Ba: ≤10 mg/kg
Bi: ≤5 mg/kg
Ca: ≤100 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤200 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Na: ≤200 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Zn: ≤5 mg/kg

absorption

cut-off at 329 nm in H2O at 1 M

SMILES string

[Li+].[O-][N+]([O-])=O

InChI

1S/Li.NO3/c;2-1(3)4/q+1;-1

InChI key

IIPYXGDZVMZOAP-UHFFFAOYSA-N

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Application


  • Revealing Lithium Nitrate-Mediated Solid-Electrolyte Interphase of Lithium Metal Anode via Cryogenic Transmission Electron Microscopy.: This study explores the role of lithium nitrate in forming the solid-electrolyte interphase (SEI) on lithium metal anodes. Using cryogenic transmission electron microscopy, the researchers revealed detailed structural and compositional insights, enhancing the understanding of lithium metal batteries (Zhen et al., 2024).

  • Three-dimensional cross-linked network deep eutectic gel polymer electrolyte with the self-healing ability enabled by hydrogen bonds and dynamic disulfide bonds.: This research presents a novel gel polymer electrolyte incorporating lithium nitrate, which facilitates a self-healing mechanism through hydrogen bonds and dynamic disulfide bonds, improving battery performance and longevity (Chen et al., 2024).

  • Additive-Driven Nanoscale Architecture of Solid Electrolyte Interphase Revealed by Cryogenic Transmission Electron Microscopy.: The study highlights how lithium nitrate, as an additive, influences the nanoscale architecture of the SEI, providing crucial insights for the design of better lithium-ion batteries (Park et al., 2024).

Pictograms

Flame over circleExclamation mark
GHS03,GHS07

Signal Word

Warning

Hazard Statements

H272 - H302 - H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 3

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Syed Nasir Abbas Bukhari et al.
Mini reviews in medicinal chemistry, 12(13), 1394-1403 (2012-08-11)
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Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 75(5), 1417-1421 (2010-03-20)
Single crystal of gamma-glycine, an organic nonlinear optical material, has been grown by solvent evaporation technique from a mixture of aqueous solutions of glycine and potassium nitrate, lithium nitrate at room temperature. Gamma glycine crystals have been grown up to
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Acta crystallographica. Section F, Structural biology and crystallization communications, 62(Pt 3), 242-244 (2006-03-03)
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