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34856

Sigma-Aldrich

Dichloromethane

suitable for HPLC, ≥99.8%, contains amylene as stabilizer

Synonym(s):

methylene chloride, Methylene chloride

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About This Item

Empirical Formula (Hill Notation):
CH2Cl2
CAS Number:
Molecular Weight:
84.93
Beilstein:
1730800
EC Number:
MDL number:
UNSPSC Code:
41116105
PubChem Substance ID:
NACRES:
NA.04

vapor density

2.9 (vs air)

Quality Level

vapor pressure

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)

Assay

≥99.8%

form

liquid

autoignition temp.

1223 °F

contains

amylene as stabilizer

expl. lim.

22 %

technique(s)

HPLC: suitable

impurities

free chlorine, in accordance
≤0.001% free acid (as HCl)
≤0.001% non-volatile matter
≤0.02% water (Karl Fischer)

color

APHA: ≤10

transmittance

235 nm, ≥20%
240 nm, ≥50%
245 nm, ≥80%
260 nm, ≥98%

refractive index

n20/D 1.424 (lit.)

bp

39.8-40 °C (lit.)

mp

−95 °C (lit.)

density

1.325 g/mL at 25 °C (lit.)

absorption

in accordance

application(s)

food and beverages

SMILES string

ClCCl

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

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General description

Dichloromethane has been tested as a solvent medium for dipyridine-chromium(VI) oxide. Solubility was reported to be 12.5g/100ml. Role of the quantity of TiO2 loading on activated carbon support on dichloromethane photodecomposition has been investigated.

Application

Dichloromethane may be used in ultrasonic baths for cleaning and protection of aluminum coating over atactic-PMMA (poly(methyl methacrylate)) for dielectric studies.

Preparation Note

Product filtered through a 0.2 μm filter

Other Notes

Pure-Pac® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.
Important notice
  • The article number 34856-4X2.5L will be discontinued. Please order the single bottle 34856-2.5L which is physically identical with the same exact specifications.
  • The article number 34855-6X1L will be discontinued. Please order the single bottle 34856-1L which is physically identical with the same exact specifications.

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Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Legal Information

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flash Point(F)

does not flash

Flash Point(C)

does not flash


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Glassy dynamics and glass transition in thin polymer layers of PMMA deposited on different substrates.
Erber M, et al.
Macromolecules, 43(18), 7729-7733 (2010)
Effect of activated carbon content in TiO2-loaded activated carbon on photodegradation behaviors of dichloromethane.
Torimoto T, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 103(1), 153-157 (1997)
Dipyridine-chromium (VI) oxide oxidation of alcohols in dichloromethane.
Collins JC, et al.
Tetrahedron Letters, 9(30), 3363-3366 (1968)
Amélie Kochem et al.
Inorganic chemistry, 51(20), 10557-10571 (2012-09-28)
Square planar cobalt(II) complexes of salen ligands N,N'-bis(3-tert-butyl-5R-salicylidene)-1,2-cyclohexanediamine), where R = OMe (1) and tert-butyl (2), were prepared. 1 and 2 were electrochemically reversibly oxidized into cations [1-H(2)O](+) and [2-H(2)O](+) in CH(2)Cl(2). The chemically generated [1-H(2)O](SbF(6))·0.68 H(2)O·0.82CH(2)Cl(2) and [2-H(2)O](SbF(6))·0.3H(2)O·0.85CH(2)Cl(2) were
Angharad M Roberts et al.
Science translational medicine, 7(270), 270ra6-270ra6 (2015-01-16)
The recent discovery of heterozygous human mutations that truncate full-length titin (TTN, an abundant structural, sensory, and signaling filament in muscle) as a common cause of end-stage dilated cardiomyopathy (DCM) promises new prospects for improving heart failure management. However, realization

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