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75712

Sigma-Aldrich

Diethyl oxalate

purum, ≥99.0% (GC)

Synonym(s):

Diethyl ethanedioate, Ethyl oxalate

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About This Item

Linear Formula:
C2H5OCOCOOC2H5
CAS Number:
Molecular Weight:
146.14
Beilstein:
606350
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

vapor density

5.03 (vs air)

Quality Level

vapor pressure

1 mmHg ( 47 °C)

grade

purum

Assay

≥99.0% (GC)

form

liquid

refractive index

n20/D 1.410 (lit.)
n20/D 1.410

bp

185 °C (lit.)

mp

−41 °C (lit.)

density

1.076 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)C(=O)OCC

InChI

1S/C6H10O4/c1-3-9-5(7)6(8)10-4-2/h3-4H2,1-2H3

InChI key

WYACBZDAHNBPPB-UHFFFAOYSA-N

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Related Categories

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

Target Organs

Kidney

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

167.0 °F - closed cup

Flash Point(C)

75 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Hina Zafar et al.
Journal of photochemistry and photobiology. B, Biology, 142, 8-19 (2014-12-10)
A condensation reaction between 1,2-diphenylethane-1,2-dione dihydrazone (DPEDDH) and dimethyl or diethyloxalate in methanol resulted in a novel Schiff base octaazamacrocyclic ligand, (L): (6,7,14,15-tetraoxa-2,3,10,11-tetraphenyl-1,4,5,8,9,12,13,16-octaazacyclohexadecane-1,3,9,11-tetraene). Subsequently metal complexes of the type [MLX2] and [CuL]X2; (M=Mn(II), Co(II), Ni(II) and Zn(II); X=Cl or NO3)

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