M9653
Methoxyacetyl chloride
97%
Synonym(s):
2-methoxyacetyl chloride, Methoxyacetic acid chloride
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About This Item
Linear Formula:
CH3OCH2COCl
CAS Number:
Molecular Weight:
108.52
Beilstein:
1740244
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
form
liquid
refractive index
n20/D 1.419 (lit.)
bp
112-113 °C (lit.)
density
1.187 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
COCC(Cl)=O
InChI
1S/C3H5ClO2/c1-6-2-3(4)5/h2H2,1H3
InChI key
JJKWHOSQTYYFAE-UHFFFAOYSA-N
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Application
Methoxyacetyl chloride can be used for methoxyacetylation of:
It can also be used for the synthesis of β-lactams by reacting with imines. and in the post-synthetic modification of the metal-organic framework (MOF), MIL-101, to synthesize a catalyst for cycloaddition reaction of CO2 with propylene oxide.
- Bilocularin A to synthesize 8-Methoxyacetoxybilocularin A.
- Substituted and unsubstituted benzamides to synthesize N-(2-methoxyacetyl)-benzamides.
It can also be used for the synthesis of β-lactams by reacting with imines. and in the post-synthetic modification of the metal-organic framework (MOF), MIL-101, to synthesize a catalyst for cycloaddition reaction of CO2 with propylene oxide.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
82.4 °F
Flash Point(C)
28 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A telescopic one-pot synthesis of ?-lactam rings using amines as a convenient source of imines.
Rajamaki SHM, et al.
Royal Society of Chemistry Advances, 6(45), 38553-38557 (2016)
Bioactive dihydro-?-agarofuran sesquiterpenoids from the Australian rainforest plant Maytenus bilocularis.
Wibowo M, et al.
Journal of Natural Products, 79(5), 1445-1453 (2016)
Functionalized MIL-101 with imidazolium-based ionic liquids for the cycloaddition of CO2 and epoxides under mild condition.
Liu D, et al.
Applied Surface Science, 428(45), 218-225 (2018)
Radu A Gropeanu et al.
PloS one, 7(9), e43657-e43657 (2012-09-13)
Three different variants of photoactivatable caged paclitaxel (PTX) have been synthesized and their bioactivity was characterized in in vitro assays and in living cells. The caged PTXs contain the photoremovable chromophore 4,5-dimethoxy-2-nitrobenzyloxycarbonyl (Nvoc) attached to position C7, C2' and to
Synthesis of Quinolinone Alkaloids via Aryne Insertions into Unsymmetric Imides in Flow.
Schwan J, et al.
Organic Letters, 20(23), 7661?7664-7661?7664 (2018)
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