ALD00232

Sodium tetrahydropyransulfinate

• Synonym(s): Baran THPS-Na Reagent, Sodium oxane-4-sulfinate
• Empirical Formula (Hill Notation): C₅H₉NaO₃S
• CAS Number: 1516140-99-0
• Molecular Weight: 172.18
• MDL number: MFCD24113367
• UNSPSC Code: 12352005
• PubChem Substance ID: 329772644
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• reaction suitability: reaction type: C-C Bond Formation; reagent type: catalyst; reaction type: C-H Activation
• SMILES string: O=S(C1CCOCC1)[O-].[Na+]
• InChI: 1S/C5H10O3S.Na/c6-9(7)5-1-3-8-4-2-5;/h5H,1-4H2,(H,6,7);/q;+1/p-1
• InChI key: JIOKFXIXTDFEIS-UHFFFAOYSA-M

Description

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Other Notes

Radical-Based Regioselective C-H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable