Skip to Content
Merck
All Photos(1)

Key Documents

703559

SAFC

Lanthanum(III) chloride bis(lithium chloride) complex solution

0.6 M in THF

Synonym(s):

Lanthanum trichloride lithium chloride complex

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
LaCl3 · 2LiCl
CAS Number:
Molecular Weight:
330.05
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reagent type: catalyst
core: lanthanum

concentration

0.6 M in THF
16 % (w/w)

density

1.05 g/mL at 25 °C

SMILES string

[Li]Cl.[Li]Cl.Cl[La](Cl)Cl

InChI

1S/5ClH.La.2Li/h5*1H;;;/q;;;;;+3;2*+1/p-5

InChI key

YSKOYVQYUJUXCN-UHFFFAOYSA-I

Application

Selective 1,2-Additions with LaCl3•2LiCl

  • Mediates Grignard additions
  • Reagent for metal exchange reactions
  • Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines

Legal Information

Product of Albemarle US Inc

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Sens. 1 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

62.6 °F

Flash Point(C)

17 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Selective 1,2-Additions with LaCl3·2LiCl

Transformative reagents for selective metalation, deprotonation and nucleophilic additions have allowed for unprecedented selective converstions to reactive intermediates within a molecule which contains sensative functionalities under mild reactions.

Sigma-Aldrich.com presents an article concerning New Reagents for Selective Metalation, Deprotonation, and 1,2-Additions.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service