477222

4-Chloroaniline

purified by sublimation, ≥99%

• Synonym(s): 1-Amino-4-chlorobenzene, 4-Chlorophenylamine, p-Chloroaniline
• Linear Formula: ClC₆H₄NH₂
• CAS Number: 106-47-8
• Molecular Weight: 127.57
• Beilstein: 471359
• EC Number: 203-401-0
• MDL number: MFCD00007835
• UNSPSC Code: 12352100
• PubChem Substance ID: 24871344
• NACRES: NA.22

Properties

• vapor density: 4.4 (vs air)
• Quality Level: 100
• vapor pressure: 0.15 mmHg ( 25 °C)
• Assay: ≥99%
• form: crystals; powder; solid
• purified by: sublimation
• bp: 232 °C (lit.)
• mp: 67-70 °C (lit.)
• functional group: chloro
• SMILES string: Nc1ccc(Cl)cc1
• InChI: 1S/C6H6ClN/c7-5-1-3-6(8)4-2-5/h1-4H,8H2
• InChI key: QSNSCYSYFYORTR-UHFFFAOYSA-N

Description

General description

4-Chloroaniline (4-ClA) is a chlorinated aromatic amine that is formed as an intermediate during the microbial decomposition of phenylurea and phenylcarbamate. The formation of various oligomers by polymerization of 4-ClA with guaiacol in an aqueous solution containing oxidoreductases has been reported. 4-ClA undergoes decomposition via oxidation by fusarium oxysporum, a soil fungus.

Application

4-Chloroaniline may be used to synthesize:

• 4-chloronitrosobenzene
• 2-bromo-4-chloroaniline
• 2,6-dibromo-4-chloroaniline

Safety Information

• Pictograms: GHS06,GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H301 + H311 + H331,H317,H350,H410
• Precautionary Statements: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Skin Sens. 1
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point(F): 248.0 °F - closed cup
• Flash Point(C): 120.0 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves