Skip to Content
Merck
All Photos(3)

Key Documents

View All Documentation

451622

Sigma-Aldrich

Lithium tetrafluoroborate

greener alternative

ultra dry, powder, 99.99% trace metals basis

Synonym(s):

Lithium borofluoride, Lithium fluoroborate

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Linear Formula:
LiBF4
CAS Number:
14283-07-9
Molecular Weight:
93.75
EC Number:
238-178-9
MDL number:
MFCD00011087
UNSPSC Code:
12352302
PubChem Substance ID:
24868639
NACRES:
NA.23

description

Grade: ultra dry

Quality Level

200

Assay

99.99% trace metals basis

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤150.0 ppm Trace Metal Analysis

mp

293-300 °C (dec.) (lit.)

application(s)

battery manufacturing

greener alternative category

, Enabling

SMILES string

[Li+].F[B-](F)(F)F

InChI

1S/BF4.Li/c2-1(3,4)5;/q-1;+1

InChI key

UFXJWFBILHTTET-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Lithium tetrafluoroborate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiBF4 is majorly used as an electrolyte with good ionic conductivity. It facilitates the formation of an electrolytic solution or a liquid electrolyte, which can be used in the fabrication of lithium-ion batteries and solid-state electrochemical displays.
Used recently in the development of a solid composite electrolyte for lithium batteries.

accessory

Product No.
Description
Pricing

related product

Product No.
Description
Pricing

450227

Lithium hexafluorophosphate, battery grade, ≥99.99% trace metals basis

757136

Lithium bis(oxalato)borate

774138

Lithium difluoro(oxalato)borate

809942

Dimethyl carbonate, battery grade, ≥99.9%, acid <10 ppm, H2O <10 ppm

809950

Ethylene carbonate, battery grade, ≥99%, acid <10 ppm, H2O <10 ppm

809969

Propylene carbonate, battery grade, ≥99%, acid <10 ppm, H2O <10 ppm

809934

Ethyl methyl carbonate, battery grade, 99.9%, acid <10 ppm, H2O <10ppm

900018

Diethyl carbonate, battery grade, ≥99%, acid <10 ppm, H2O <10 ppm

901686

Fluoroethylene carbonate, battery grade, ≥99%, acid <200 ppm, anhydrous

919977

Lithium bis(trifluoromethanesulfonyl)imide, anhydrous, 99.99% trace metals basis

Signal Word

Danger

Hazard Statements

H302,H314,H341

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCQ8580
MKCQ1191
MKCM5192
MKCM8671
MKCK7601

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Application of di-ureasil ormolytes based on lithium tetrafluoroborate in solid-state electrochromic displays
Barbosa P, et al.
Journal of Materials Chemistry, 20(4), 723-730 (2010)
Zachary T Gossage et al.
The Analyst, 145(7), 2631-2638 (2020-02-27)
Interphases formed at battery electrodes are key to enabling energy dense charge storage by acting as protection layers and gatekeeping ion flux into and out of the electrodes. However, our current understanding of these structures and how to control their
A new lithium salt with dihydroxybenzene and lithium tetrafluoroborate for lithium battery electrolytes
Xue Z, et al.
Journal of Power Sources, 196(20), 8710-8713 (2011)
Proc. Power Sources Conf., 37th, 287-287 (1996)
Takahiro Ichikawa et al.
Journal of the American Chemical Society, 133(7), 2163-2169 (2011-01-29)
Thermotropic bicontinuous cubic (Cub(bi)) liquid-crystalline (LC) compounds based on a polymerizable ammonium moiety complexed with a lithium salt have been designed to obtain lithium ion-conductive all solid polymeric films having 3D interconnected ionic channels. The monomer shows a Cub(bi) phase
View All Related Papers

Articles

Nanomaterials for Energy Storage in Lithium-ion Battery Applications

Nanomaterials for Energy Storage in Lithium-ion Battery Applications

U.S. Department of Energy’s Materials Research for Advanced Lithium Ion Batteries

Increasing fuel costs and concerns about greenhouse gas emissions have spurred the growth in sales of hybrid electric vehicles (HEVs) that carry a battery pack to supplement the performance of the internal combustion engine (ICE).

Solid-State Rechargeable Batteries

Dr. Sun reviews the recent advances in solid-state rechargeable batteries and cover the fundamentals of solid electrolytes in solid-state batteries, the theory of ion conduction, and the structures and electrochemical processes of solid-state Li batteries.

Electrode Materials for Lithium Ion Batteries

Electrode Materials for Lithium Ion Batteries

See All

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service