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109576

Sigma-Aldrich

1,1′-Dimethylferrocene

95%

Synonym(s):

Bis(methylcyclopentadienyl)iron

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About This Item

Empirical Formula (Hill Notation):
C12H14Fe
CAS Number:
1291-47-0
Molecular Weight:
214.08
EC Number:
215-067-3
MDL number:
MFCD00001425
UNSPSC Code:
12161600
PubChem Substance ID:
24846924
NACRES:
NA.22

Quality Level

100

Assay

95%

form

solid

reaction suitability

core: iron
reagent type: catalyst

mp

37-40 °C (lit.)

SMILES string

[Fe].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2

InChI

1S/2C6H7.Fe/c2*1-6-4-2-3-5-6;/h2*2-5H,1H3;

InChI key

GJFIEPAJMYPAGC-UHFFFAOYSA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

226.4 °F - closed cup

Flash Point(C)

108.00 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBV1343V
MKBT9556V
MKBQ4521V
MKBN3832V
MKBG8710V

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D J Claremont et al.
Diabetologia, 29(11), 817-821 (1986-11-01)
Miniature, amperometric glucose sensors were constructed using entrapped 1,1'-dimethylferrocene to mediate electron transfer between immobilised glucose oxidase and a carbon base electrode. Electrodes were calibrated in buffered glucose solutions and then implanted in the subcutaneous tissue of anaesthetised, non-diabetic pigs.
[Electrocatalytic oxidation of substrates by immobilized Gluconobacter oxydans cells in the presence of an electron transport mediator].
A N Reshetilov et al.
Doklady Akademii nauk, 358(2), 263-265 (1998-04-29)
M Wenzel et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 43(11-12), 963-966 (1988-11-01)
The relative stabilities of different ferricinium cations were studied in buffer or serum-containing solution and in vivo and compared with their cytostatic effects in cultures of Yoshida ascites tumor cells. Although the ferricinium cation itself was the most unstable cation
P C Pandey et al.
Analytical biochemistry, 252(1), 136-142 (1997-11-05)
This article describes the research investigations on the development of the amperometric biosensors based on mediated bioelectrochemistry. The mediated bioelectrochemistry involving horseradish peroxidase and glucose oxidase within the graphite paste is reported. The enzyme horseradish peroxidase together with electrochemical mediator
K B Male et al.
Applied biochemistry and biotechnology, 44(1), 91-100 (1994-01-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (Hp-beta-CyD), a cyclic and nonreducing oligosaccharide was used to enclose a hydrophobic guest molecule 1,1'-dimethylferrocene (DMF) to form a water-soluble yellow complex. At high concentrations (300 mM), Hp-beta-CyD enclosed up to 100 mM DMF. The yellow complex was
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