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P6863

Sigma-Aldrich

PDAM

≥70% purity (HPLC), for HPLC derivatization, solid

Synonyme(s) :

1-Pyrenyldiazomethane, Pyrene, 1-(diazomethyl)

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About This Item

Formule empirique (notation de Hill):
C17H10N2
Numéro CAS:
78377-23-8
Poids moléculaire :
242.27
Numéro MDL:
MFCD00467268
Code UNSPSC :
12171500
ID de substance PubChem :
329820256
Nomenclature NACRES :
MA.02

product name

PDAM, for HPLC derivatization

Qualité

for HPLC derivatization

Niveau de qualité

200

Pureté

≥70% (HPLC)

Forme

solid

λmax

338-344 nm

Fluorescence

λem 371-379 nm

Application(s)

diagnostic assay manufacturing
hematology
histology

Conditions d'expédition

dry ice

Température de stockage

−20°C

Chaîne SMILES 

[N-]=[N+]=Cc1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C17H10N2/c18-19-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-10H

Clé InChI

PEIBAWRLFPGPAT-UHFFFAOYSA-N

Catégories apparentées

Application

Fluorescent diazoalkane useful as an HPLC derivatization reagent for carboxylic acid detection with better detection limit parameters and greater chemical stability than the commonly used 9-anthryldiazomethane.

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Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type N95 (US)

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Certificats d'analyse (COA)

Lot/Batch Number
SLCL7145
SLCK1755
SLCF2117
SLCF2110
SLCC5470

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Consulter la Bibliothèque de documents

Carlos García et al.
Biological research, 36(2), 171-183 (2003-09-30)
Diarrhetic shellfish poisoning (DSP) is a gastrointestinal disease caused by lipid soluble polyether toxins produced by dinoflagellates and accumulated in shellfish. Diarrhetic shellfish poisoning is a worldwide threat to public health and the shellfish industry. To date, only four lipid
F Iohan et al.
Journal of chromatography, 564(1), 27-41 (1991-03-08)
A new procedure is described for the detection of the acidic metabolites of cortisol (cortoic acids) as the pyrenylmethyl-21-oic esters. The derivatizing reagent, diazomethylpyrene, was prepared by an improved procedure. The reagent was used at room temperature, required no catalyst
Liquid chromatographic determination of biotin by using 1-pyrenyldiazomethane as a pre-column fluorescent labelling reagent.
T Yoshida et al.
Journal of chromatography, 456(2), 421-426 (1988-12-16)
O L Brekke et al.
Journal of lipid research, 38(9), 1913-1922 (1997-11-05)
A highly sensitive method to determine agonist-induced release of endogenous fatty acids from cells in culture was developed using high-performance liquid chromatography and fluorescence detection. Fatty acids were selectively derivatized with 1-pyrenyldiazomethane and separated on a LC18 reversed phase column
Junko Amano et al.
Analytical chemistry, 82(20), 8738-8743 (2010-09-25)
Glycoproteomics holds the promise of new advances in medical technology. However, mass spectrometry has limitations for the structural determination of glycosylated peptides because the hydrophilic nature of the oligosaccharide moiety in glycopeptides is disadvantageous for ionization, and glycopeptides ionize much
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