42215

2,4-Dinitrophenylhydrazine Phosphoric acid solution

for derivatization (of aldehydes and ketones), LiChropur^™, substitute for the explosive solid, ~0.2 M (~4%)

• Formule empirique (notation de Hill): C₆H₆N₄O₄
• Numéro CAS: 125038-14-4
• Poids moléculaire : 198.14
• Numéro Beilstein : 6258433
• Numéro MDL: MFCD01863021
• Code UNSPSC : 41116105
• ID de substance PubChem : 329756206
• Nomenclature NACRES : NA.22

Propriétés

• Qualité: for derivatization (of aldehydes and ketones); LiChropur^™
• Forme: liquid
• Composition: 2,4-dinitrophenylhydrazine ; ethanol ; phosphoric acid
• Concentration: ~0.2 M (~4%)
• Technique(s): thin layer chromatography (TLC): suitable
• Densité: 1.35 g/mL at 20 °C
• Chaîne SMILES: OP(O)(O)=O.NNc1ccc(cc1[N+]([O-])=O)[N+]([O-])=O
• InChI: 1S/C6H6N4O4.H3O4P/c7-8-5-2-1-4(9(11)12)3-6(5)10(13)14;1-5(2,3)4/h1-3,8H,7H2;(H3,1,2,3,4)
• Clé InChI: RYSWHUOYGUCXQB-UHFFFAOYSA-N

Description

Application

• Visible-light excitable Eu(3+)-induced hyaluronic acid-chitosan aggregates with heterocyclic ligands for sensitive and fast recognition of hazardous ions: Utilizes 1,10-phenanthroline monohydrate in environmental sensing applications to detect hazardous ions efficiently (Aleem AR, Ding W, Liu J, Li T, Guo Y, Wang Q, Wang Y, Rehman FUL, Kipper MJ, Belfiore LA, Tang J, 2021).


• Structural diversity of copper(I) complexes formed by pyrrole- and dipyrrolylmethane-based diphosphine ligands with cu-X···HN hydrogen bonds: Researches the coordination chemistry of 1,10-phenanthroline monohydrate, highlighting its role in forming novel copper(I) complexes (Kumar S, Mani G, Dutta D, Mishra S, 2014).


• Direct electron transfer from glucose oxidase immobilized on polyphenanthroline-modified glassy carbon electrode: Demonstrates the use of 1,10-phenanthroline monohydrate in biosensor applications for direct electron transfer mechanisms (Oztekin Y, Ramanaviciene A, Yazicigil Z, Solak AO, Ramanavicius A, 2011).

Autres remarques

Reagent for derivatizing aldehydes and ketones, replacement for the explosive solid

Informations légales

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Informations sur la sécurité

• Pictogrammes: GHS02,GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H226,H290,H302,H314
• Conseils de prudence: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Corr. 1B
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 86.0 °F
• Point d'éclair (°C): 30 °C
• Équipement de protection individuelle: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter