903973

Thianthrene S-oxide

≥95%

• Synonyme(s) : Non-fluorinated sulfoxide-based thianthrene reagent, Thianthrene 5-oxide
• Formule empirique (notation de Hill): C₁₂H₈OS₂
• Numéro CAS: 2362-50-7
• Poids moléculaire : 232.32
• Numéro MDL: MFCD01464038
• Code UNSPSC : 12352119
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: ≥95%
• Forme: powder
• Groupe fonctionnel: sulfoxide; thioether
• Température de stockage: 2-8°C
• InChI: 1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H
• Clé InChI: NYVGTLXTOJKHJN-UHFFFAOYSA-N

Description

Application

Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent.

Autres remarques

Site-selective and versatile aromatic C-H functionalization by thianthrenation

Video: Site-selective C-H functionalization by thianthrenation

In the Pipeline: New Chemistry, Making New Things

Ti(Phen)(OC₂H₅)₂Cl₂: a highly efficient pre-?catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide

Informations légales

Patent Application EP18204755.5
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable