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763705

Sigma-Aldrich

Graphene oxide

greener alternative

2 mg/mL, dispersion in H2O, avg. no. of layers, 1

Synonyme(s) :

graphene oxide aqueous dispersion

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About This Item

Formule linéaire :
CxOyHz
Code UNSPSC :
12352103
Nomenclature NACRES :
NA.23

Forme

dispersion in H2O

Niveau de qualité

Caractéristiques

avg. no. of layers 1

Caractéristiques du produit alternatif plus écologique

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

Concentration

2 mg/mL

Indice de réfraction

n20/D 1.333

Densité

0.981 g/mL at 25 °C

Autre catégorie plus écologique

Chaîne SMILES 

O=C(O)C1C2=C3C4=C5C6=C7C8=C9C%10=C%11C(C%12=C%13C%10=C%14C8=C%15C6=C%16C4=C%17C2=CC(C(O)=O)C%18=C%17C%19=C%16C%20=C%15C%21=C%14C%22=C%13C(C%23=C%24C%22=C%25C%21=C%26C%20=C%27C%19=C%28C%18=CC(C(O)=O)C%29=C%28C%30=C%27C%31=C%26C%32=C%25C%33=C%24C(C%34=C%35C

InChI

1S/C140H42O20/c141-131(142)26-13-23-15-44-62(140(159)160)45-16-24-14-40-31(132(143)144)5-1-29-41-20-48(135(149)150)56-33-7-3-28-27-2-6-32-55-37(133(145)146)11-9-35-60(138(155)156)42-17-25-18-43-61(139(157)158)36-10-12-38(134(147)148)58-46-21-50(137(153)154)59-47-22-49(136(151)152)57-34-8-4-30-39(19-26)51(23)78-72(44)88-75(45)80-52(24)79(54(29)40)95-71(41)83(56)101-93-69(33)64(28)91-90-63(27)68(32)92-86(66(35)55)73(42)81-53(25)82-74(43)87(67(36)58)96-76(46)85(59)103-97-77(47)84(57)102-94-70(34)65(30)89(78)105-104(88)115-98(80)111(95)116(101)126-122-110(93)107(91)120-119-106(90)108(92)99(81)114-100(82)112(96)118(103)128(124(114)119)123-113(97)117(102)127(130(122)129(120)123)121(109(94)105)125(115)126/h2,5,7-10,12-22,26,38,48-50H,1,3-4,6,11H2,(H,141,142)(H,143,144)(H,145,146)(H,147,148)(H,149,150)(H,151,152)(H,153,154)(H,155,156)(H,157,158)(H,159,160)

Clé InChI

VTWITIAIMADGRM-UHFFFAOYSA-N

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Description générale

  • Chloride free (purified by dialysis)
  • Monolayer sheet
  • sheet diameter <10 micron
Graphene oxide (GO) is a one atom thick 2D carbon material with excellent thermal, mechanical, and electrical properties due to its unique structural and morphological features. GO can be easily dispersed in aqueous and polar organic solvents to facilitate its practical use. It can be synthesized by modified Hummer’s method. It can be applied in the fields of drug delivery, energy storage, oil-water separation, immobilization catalysis, desalination, and solar cells.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". High concentrated graphene oxide sheets provide the prerequisite viscosity to bind the electrode materials together and enable 3D printing. Using water as a green solvent makes this aqueous ink system feasible for processing and drying safety and low cost. Click here for more information.

Application

Because of the presence of oxygen-containing functional groups and acidic nature, GO can serve as both carbocatalyst as well as a supporting scaffold for various catalytically active species. GO can facilitate many organic transformations such as the oxidation of sulfides, olefins, and various hydrocarbons, Friedel–Crafts reaction, Aza–Michael additions, condensation, and ring-opening polymerization.

It can be used as a support for biocatalysis in organic solvents. For example, carboxyl-functionalized graphene oxide can act as a support to immobilize Yarrowia lipolytica lipase. The immobilized enzyme exhibits a high efficiency for the resolution of the racemic compound in the organic solvent.

It can also be used as a hole transport layer in organic photovoltaic cells.

Caractéristiques et avantages

  • Good solution processability
  • Hydrophilic and easily dispersed in water
  • Low production cost
  • Presence of rich active oxygen-containing functional groups
  • It can be easily functionalized
Large surface area, high chemical stability, good charge carrier properties.

Notes préparatoires

Product may aggregate over time to form larger particles. Sonicate before use if single layer graphene oxide required.

Code de la classe de stockage

10 - Combustible liquids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Nitish Sathyanarayanan et al.
Nature communications, 10(1), 4127-4127 (2019-09-13)
Substrate channeling is a mechanism for the internal transfer of hydrophobic, unstable or toxic intermediates from the active site of one enzyme to another. Such transfer has previously been described to be mediated by a hydrophobic tunnel, the use of
Goki Eda et al.
Advanced materials (Deerfield Beach, Fla.), 22(22), 2392-2415 (2010-05-01)
Chemically derived graphene oxide (GO) possesses a unique set of properties arising from oxygen functional groups that are introduced during chemical exfoliation of graphite. Large-area thin-film deposition of GO, enabled by its solubility in a variety of solvents, offers a
N-doped graphitic self-encapsulation for high performance silicon anodes in lithium-ion batteries.
JunaLee, Won, et al.
Energy & Environmental Science, 7(2), 621-626 (2014)
Toward N-doped graphene via solvothermal synthesis
Deng, Dehui, et al.
Chemistry of Materials, 23(5), 1188-1193 (2011)
Chemically modified graphene and nitrogen-doped graphene: Electrochemical characterisation and sensing applications
Prathish, Krishna P., et al.
Electrochimica Acta, 114, 533-542 (2013)

Articles

Graphene oxide is a unique material that can be viewed as a single monomolecular layer of graphite with various oxygen containing functionalities such as epoxide, carbonyl, carboxyl and hydroxyl groups.

Carbon nanomaterials (CNMs), such as single-walled carbon nanotubes (SWCNTs), multi-walled carbon nanotubes (MWCNTs), and graphene (Figure 1), have diverse commercial applications including lighter and stronger composite materials, improved energy storage devices, more sensitive sensors, and smaller transistors.

Professor Rivnay (Northwestern University, USA) discusses using organic mixed conductors as an alternative to efficiently bridge the ionic world of biology with contemporary microelectronics.

Developed in the last several years, fluorescence quenching microscopy (FQM) has enabled rapid, inexpensive, and high-fidelity visualization of two-dimensional (2D) materials such as graphene-based sheets and MoS2.

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