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Merck
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Key Documents

Autres documents

733350

Sigma-Aldrich

Bis[2-(2-bromoisobutyryloxy)undecyl] disulfide

97%

Synonyme(s) :

11,11′-Dithiobis[1-(2-bromo-2-methylpropionyloxy)undecane], DTBU

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About This Item

Formule empirique (notation de Hill):
C30H56Br2O4S2
Numéro CAS:
402828-41-5
Poids moléculaire :
704.70
Code UNSPSC :
12162002
ID de substance PubChem :
329764807
Nomenclature NACRES :
NA.23

Pureté

97%

Forme

solid

Solubilité

1.500 at 20 °C

Densité

1.177 g/mL at 25 °C

Chaîne SMILES 

CC(C)(Br)C(=O)OCCCCCCCCCCCSSCCCCCCCCCCCOC(=O)C(C)(C)Br

InChI

1S/C30H56Br2O4S2/c1-29(2,31)27(33)35-23-19-15-11-7-5-9-13-17-21-25-37-38-26-22-18-14-10-6-8-12-16-20-24-36-28(34)30(3,4)32/h5-26H2,1-4H3

Clé InChI

IEGYEGYUHSQEAZ-UHFFFAOYSA-N

Application

Atom transfer Radical Polymerisation (ATRP) initiator commonly used to functionalize noble metal surfaces, and in the preparation of polymer brushes and biodegradable hydrogels. Also may be used to introduce a temperature and light sensitive cleavable region into the polymer.

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Mentions de danger

H315,H319,H335

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Certificats d'analyse (COA)

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Shuai Zhao et al.
Proceedings of the National Academy of Sciences of the United States of America, 114(35), E7245-E7254 (2017-08-16)
Chemical modifications on histones and DNA/RNA constitute a fundamental mechanism for epigenetic regulation. These modifications often function as docking marks to recruit or stabilize cognate "reader" proteins. So far, a platform for quantitative and high-throughput profiling of the epigenetic interactome
Rui Yatabe et al.
Sensors (Basel, Switzerland), 13(7), 9294-9304 (2013-07-24)
In this study, we modified a surface plasmon resonance immunosensor chip with a polymer using surface-initiated atom transfer polymerization (SI-ATRP) for the highly sensitive detection of 2,4,6-trinitrotoluene (TNT). To immobilize a TNT analogue on the polymer, mono-2-(methacryloyloxy)ethylsuccinate (MES), which has

Articles

ATRP: Complete Tools for the Synthesis of Well-Defined, Functionalized Polymers

Find how atom transfer radical polymerization (ATRP) tools can be used for the synthesis of well-defined functionalized polymers.

ATRP: Complete Tools for the Synthesis of Well-Defined Functionalized Polymers

ATRP polymerization, chain transfer agent, living polymerization, functional telechelic polymers

ATRP Ligands and Initiators for the Clean Synthesis of Functional Polymers

Atom transfer radical polymerization (ATRP) has emerged as one of the most successful synthetic techniques for the preparation of polymers with predetermined molecular weights, narrow molecular weight distributions, and high degrees of chain end functionalities.

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

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Protocoles

Typical Procedures for Polymerizing via ATRP

An article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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